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KMID : 0604520190450030217
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Journal of the Society of Cosmetic Scientists of Korea
2019 Volume.45 No. 3 p.217 ~ p.224
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A Study on Phthalate Analysis of Nail Related Products
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Park Shin-Hee
Song Seo-Hyeon
Kim Hyun-Joo
Cho Yoon-Sik
Kim Ae-Ran
Kim Beom-Ho
Hong Mi-Yeon
Park Sang-Hyun
Yoon Mi-Hye
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Abstract
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Phthalates, endocrine disrupting chemicals, are similar in structure to sex hormones and mainly show reproductive toxicity and developmental toxicity. In this study, we analyzed 11 phthalates, including 3 kinds of phthalates prohibited in cosmetic use and 8 kinds of phthalates regulated in ‘Common standards for children’s products safety’ and EU cosmetic regulation (EC No. 1223/2009). The phthalate analysis was optimized using GC-MS/MS. In analytical method validation, this method was satisfied in specificity, linearity, recovery rate, accuracy and MQL. Therefore, we used this method to analyze 82 products of Nail cosmetics & polish. Although six phthalates such as DBP, BBP, DEHP, DPP, DIBP and DIDP were detected at concentrations of 1.0 ∼ 59.8 ㎍/g, they were suitable to Korean cosmetic standards. DIBP and DBP were detected at concentration of 1.1 ∼ 2.6 ㎍/g in artificial nail, DBP and DEHP were 1.4 ∼ 2.5 ㎍/g in glue for nails, and DIBP, DBP, and DEHP were 2.5 ∼ 33.3 ㎍/g in nail stickers. Although substances such as DBP and DEHP in artificial nail, Glue for nails, and nail stickers were detected, they were suitable to ‘Common safety standards for children’s products. DIBP is not a regulated substance in Korea but showed the third highest detection rate following DBP (84.6%) and DEHP (63.4%). The concentration of phthalates detected in nail products is considered to be safe in current standards but continuous monitoring and research about non-regulated substances are also needed to be considered.
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KEYWORD
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nail polish, phthalates, cosmetic regulations, GC-MS/MS, validations
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